Product Details of 676525-77-2. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: [Ir(dtbbpy)(ppy)2]PF6, is researched, Molecular C40H40F6IrN4P, CAS is 676525-77-2, about Visible-Light Photoredox Catalysis: Aza-Henry Reactions via C-H Functionalization. Author is Condie, Allison G.; Gonzalez-Gomez, Jose C.; Stephenson, Corey R. J..
The authors report the application of visible-light photoredox catalysis for the formation of C-C bonds between tertiary N-arylamines and nitroalkanes via an oxidative aza-Henry reaction. In the presence of 1 mol % Ir(ppy)2(dtbbpy)PF6, efficient coupling of nitroalkanes with in situ-generated iminium ions provides the desired products in up to 96% yield. Mechanistic studies suggest that reductive quenching of the Ir3+ excited state by the tertiary amine leads to the ammonium radical cation, with subsequent catalyst turnover (Ir2+ → Ir3+) likely effected by atm. oxygen.
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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”