Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: [Ir(dtbbpy)(ppy)2]PF6, is researched, Molecular C40H40F6IrN4P, CAS is 676525-77-2, about Accelerated luminophor discovery through combinatorial synthesis.Synthetic Route of C40H40F6IrN4P.
A method for accelerating the discovery of ionic luminophors using combinatorial techniques is reported. The photophys. properties of the resulting transition-metal-based chromophores were compared against analogous, traditionally prepared species. The strong overlap between these two sets confirms the identity of the parallel synthesis products and supports the truthfulness of the combinatorial results. Further support for the combinatorial method comes from the adherence of these complexes to the energy gap law. The relation between the structure of a complex and its photophys. properties was also considered, and static DFT calculations were used to assess whether it is feasible to predict the luminescent behavior of novel materials.
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Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”