The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: [Ir(dtbbpy)(ppy)2]PF6, is researched, Molecular C40H40F6IrN4P, CAS is 676525-77-2, about Discovery of an α-Amino C-H Arylation Reaction Using the Strategy of Accelerated Serendipity, the main research direction is photoredox catalyst arylation tertiary amine cyano aromatic; serendipitous preparation benzylic amine.HPLC of Formula: 676525-77-2.
Serendipity has long been a welcome yet elusive phenomenon in the advancement of chem. We sought to exploit serendipity as a means of rapidly identifying unanticipated chem. transformations. By using a high-throughput, automated workflow and evaluating a large number of random reactions, we have discovered a photoredox-catalyzed C-H arylation reaction for the construction of benzylic amines, an important structural motif within pharmaceutical compounds that is not readily accessed via simple substrates. The mechanism directly couples tertiary amines with cyano aromatics by using mild and operationally trivial conditions.
In addition to the literature in the link below, there is a lot of literature about this compound([Ir(dtbbpy)(ppy)2]PF6)HPLC of Formula: 676525-77-2, illustrating the importance and wide applicability of this compound(676525-77-2).
Reference:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”