Xi, Lu et al. published their research in Dalton Transactions in 2022 | CAS: 14781-45-4

copper(ii)hexafluor-2,4-pentanedionate (cas: 14781-45-4) belongs to copper catalysts. The evolution of transition metal catalysts has attained a stage of civilization that authorizes for an extensive scope of chemical bonds formation partners to be combined efficiently. The copper-mediated C-C, C-O, C-N, and C-S bond formation is a part of one oldest reaction, emphasizing the Ullmann cross-coupling reaction.Computed Properties of C10H2CuF12O4

Supramolecular heptanuclear Ln-Cu complexes involving nitronyl nitroxide biradicals: structure and magnetic behavior was written by Xi, Lu;Jin, Chao-Yi;Song, Hong-Wei;Wang, Xiao-Tong;Li, Li-Cun;Sutter, Jean-Pascal. And the article was included in Dalton Transactions in 2022.Computed Properties of C10H2CuF12O4 This article mentions the following:

Four novel heptanuclear Ln-Cu complexes with the formula [Ln2Cu(hfac)8(NITPhTzbis)2][LnCu(hfac)5(NITPhTzbis)]2 (LnCu = YCu 1, TbCu 2, DyCu 3 and HoCu 4; hfac = hexafluoroacetylacetonate) were successfully constructed by employing the triazole functionalized nitronyl nitroxide biradical ligand NITPh-Tzbis (NITPh-Tzbis = 5-(1,2,4-triazolyl)-1,3-bis(1′-oxyl-3′-oxido-4′,4′,5′,5′-tetramethyl-4,5-hydro-1H-imidazol-2-yl)benzene). These hetero-tri-spin complexes are composed of two biradical-bridged dinuclear [LnCu(hfac)5(NITPhTzbis)] units and one trinuclear [Ln2Cu(hfac)8(NITPhTzbis)2] unit which form a heptanuclear supramol. structure through π-π interactions. Magnetic susceptibility investigations indicate that ferromagnetic exchange interactions dominate at low temperature for this supramol. system which can be attributed to the Ln-nitroxide exchange and intramol. NIT···NIT coupling mediated by the m-phenylene moiety. The DyCu derivative was found to exhibit a slow magnetic relaxation behavior. In the experiment, the researchers used many compounds, for example, copper(ii)hexafluor-2,4-pentanedionate (cas: 14781-45-4Computed Properties of C10H2CuF12O4).

copper(ii)hexafluor-2,4-pentanedionate (cas: 14781-45-4) belongs to copper catalysts. The evolution of transition metal catalysts has attained a stage of civilization that authorizes for an extensive scope of chemical bonds formation partners to be combined efficiently. The copper-mediated C-C, C-O, C-N, and C-S bond formation is a part of one oldest reaction, emphasizing the Ullmann cross-coupling reaction.Computed Properties of C10H2CuF12O4

Referemce:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”