Quality Control of Cupric bromideIn 2021 ,《A one-step synthesis of ultra-long silver nanowires with ultra-high aspect ratio above2000 and its application in flexible transparent conductive electrodes》 was published in Nanotechnology. The article was written by Zhang, Lu; Jiang, Fuliang; Wu, Bisheng; Lv, Chencheng; Wu, Minghua. The article contains the following contents:
Silver nanowires (AgNWs), appear as an extremely promising candidate for the next generation of flexible transparent conductive electrodes (FTCEs). However, the performance of AgNWs-FTCEs was severely limited by the aspect ratio of AgNWs, while it was still a big challenge to fabricate AgNWs with high aspect ratio nowadays. To improve the aspect ratio of AgNWs, bromide ion (Br-), cupric ion (Cu2+) and polyvinylpyrrolidone (PVP, Mw≈1300 000) which are beneficial for the synthesis of high aspect ratio AgNWs, were introduced in this article. The high quality and uniform AgNWs with the average diameter of 77.6 nm and the aspect ratio above 2000 were fabricated via a one-step solvothermal method. The effects of reaction time, molar ratio of AgNO3 to PVP and the concentration of CuBr2 on the aspect ratio of AgNWs were discussed. The mechanism of the synthesis of high aspect ratio AgNWs was explored. After that, the prepared AgNWs were spin-coated on the surface of PET film, the FTCEs based on the ultra-high aspect ratio AgNWs without any post-treatments exhibits relatively high transmittance, low haze and low sheet resistance, and the AgNWs have little effect on the optical performance of pristine PET film. The outstanding performance of the prepared FTCEs indicated that the ultra-high aspect ratio AgNWs are ideal materials in the application of FTCEs, and the method of fabricating AgNWs could provide a direction to the high aspect ratio AgNWs. The experimental part of the paper was very detailed, including the reaction process of Cupric bromide(cas: 7789-45-9Quality Control of Cupric bromide)
Some reported applications of Cupric bromide(cas: 7789-45-9) are: catalyst in cross coupling reactions; co-catalyst in Sonogashira coupling; lewis acid in enantioselective addition of alkynes.Quality Control of Cupric bromide
Referemce:
Copper catalysis in organic synthesis – NCBI,
Special Issue “Fundamentals and Applications of Copper-Based Catalysts”